Original Paper

45.  K. Kinoshita, Y. Yang, S. Nagano, S. Horiuchi,* K. Omoto, Y. Nakao, E. Sakuda, Y. Arikawa, K. Umakoshi* in preparation

44. S. Horiuchi,* S. Ogura, Y. Ikemoto, G. Watanabe, Y. Harada, in preparation

43. Y. Yang, S. Moon, S. Horiuchi,* K. Omoto, E. Sakuda, Y. Arikawa, K. Umakoshi* in preparation

42. Extension of Pt–Ag Cluster Units by Incorporating Silver Salts. Y. Yang, S. Horiuchi,* K. Omoto, E. Sakuda, Y. Arikawa, K. Umakoshi* Chem. Lett. 53, 1–4 (2024). [DOI: 10.1093/chemle/upad004 ]

41. Stepwise Sulfite Reduction on a Dinuclear Ruthenium Complex Leading to Hydrogen Sulfide. Y. Arikawa,* M. Yamada, N. Takemoto, T. Nagaoka, Y. Tsujita, T. Nakamura, Y. Tsuruta, S. Horiuchi, E. Sakuda, K. Yoshizawa, K. Umakoshi J. Am. Chem. Soc. 145, 21719–21732 (2023). [DOI: 10.1021/jacs.3c07248]

40. Engineering Soluble Diketopyrrolopyrrole Chromophore Stacks from a Series of Pd(II)-based Ravels. I. Regeni, R. Chowdhury, K. Terlinden, S. Horiuchi, J. J. Holstein, S. Feldmann, G. H. Clever* Angew. Chem. Int. Ed. 62, e202308288 (2023). [DOI: 10.1002/anie.202308288]

39. Noncovalent Tailoring of Coordination Complexes by Resorcin[4]arene-Based Supramolecular Hosts. S. Horiuchi,* M. Hayashi, K. Umakoshi* Dalton Trans. 52, 6604–6618 (2023). [DOI: 10.1039/D3DT00710C]

38. Maximized axial helicity in a Pd2L4 cage: inverse guest size-dependent compression and mesocate isomerism. W. M. Bloch,* S. Horiuchi, J. J. Holstein, C. Drechsler, A. Wuttke, W. Hiller, R. A. Mata, G. H. Clever* Chem. Sci. 14, 1524–1531 (2023). [DOI: 10.1039/D2SC06629G]

37. Symmetry-Breaking Host–guest Assembly in a Hydrogen-bonded Supramolecular System. S. Horiuchi,* T. Yamaguchi, J. Tessarolo, H. Tanaka, E. Sakuda, Y. Arikawa, E. Meggers, G. H. Clever,* K. Umakoshi* Nat. Commun. 14, 155 (2023). [DOI: 10.1038/s41467-023-35850-4]
Featured in Editor’s Highlights webpage and Science Japan.

36. Recent Advances in Pyrazolato-bridged Homo- and Heterometallic Polynuclear Platinum and Palladium Complexes. S. Horiuchi, K. Umakoshi* Coord. Chem. Rev. 476, 214924 (2023). [DOI: 10.1016/j.ccr.2022.214924]

35. Rational Synthesis of An Unsymmetric Pt Complex Unit Having Two Kinds of Pyrazolate Ligands, Elucidating Steric and Electronic Effects of Pyrazolate Ligands in Pt–Ag Sandwich Complexes. S. Horiuchi,* Y. Yang, M. Ueda, E. Sakuda, Y. Arikawa, K. Umakoshi* Eur. J. Inorg. Chem. 2022, e202200497 (2022) [DOI: 10.1002/ejic.202200497]

34. Kinetically controlled narcissistic self-sorting of Pd(II)-linked self-assemblies from structurally similar tritopic ligands. T. Abe, S. Horiuchi, S. Hiraoka* Chem. Commun. 58, 10829–10832. (2022). [DOI: 10.1039/D2CC04496J]

33. Characterization of a half-bent RuNO mode on a dinuclear ruthenium complex through reduction reaction. Y. Arikawa,* M. Yamada, Y. Otsubo, Y. Takeuchi, A. Ikeda, S. Horiuchi, E. Sakuda, K. Umakoshi Bull. Chem. Soc. Jpn. 95, 1214–1216 (2022). [DOI: 10.1246/bcsj.20220125]

32. An Asymmetric Pt Diimine Acetylide Complex Providing Unique Luminescent Multinuclear Sandwich Complexes with Cu Salts. S. Horiuchi,* H. Hiroiwa, E. Sakuda, Y. Arikawa, K. Umakoshi* Chem. Commun. 58, 3489–3492 (2022). [DOI: 10.1039/D1CC07108D]

31. A Family of Heterobimetallic Cubes Shows Spin-crossover Behavior Near Room Temperature. M. Hardy, J. Tessarolo, J. J. Holstein, N. Struch, N. Wagner, R. Weisbarth, M. Engeser, J. Beck, S. Horiuchi, G. H. Clever, A. Lützen* Angew. Chem. Int. Ed. 60, 22562–22569 (2021). [DOI: 10.1002/anie.202108792]

30. Multinuclear Ag Clusters Sandwiched by Pt Complex Units: Fluxional Behavior and Chiral-at-Cluster Photoluminescence. S. Horiuchi,* S. Moon, A. Ito, J. Tessarolo, E. Sakuda, Y. Arikawa, G. H. Clever, K. Umakoshi* Angew. Chem. Int. Ed. 60, 10654–10660 (2021). [DOI: 10.1002/anie.202101460]
Featured in the cover.

29. Bridging-Arylene Effects on Spectroscopic and Photophysical Properties of Arylborane–Dipyrrinato Zinc(II) Complexes. K. Takaki, E. Sakuda,* A. Ito, S. Horiuchi, Y. Arikawa, K. Umakoshi* RSC Advances. 11, 6259–6267 (2021). [DOI: 10.1039/d0ra09029h]

28. NO Migratory Insertion into Ruthenium–Aryl Bond with a Hydridotris(pyrazolyl)borato Ligand. Y. Arikawa,* M. Yamada, N. Takemoto, S. Horiuchi, E. Sakuda, K. Umakoshi* Organometallics. 40, 302–305 (2021). [DOI: 10.1021/acs.organomet.0c00694]

27. A Heteropolynuclear Pt-Ag System Having Cycloplatinated Rollover Bipyridyl Units. S. Horiuchi, S. Tanaka, S. Moon, E. Sakuda, A. Ito, Y. Arikawa, K. Umakoshi* Inorg. Chem. 60, 1513–1522 (2021). [DOI: 10.1021/acs.inorgchem.0c02843]

26. Emissive Supramolecular Systems Based on Reversible Bond Formation and Noncovalent Interactions. S. Horiuchi,* K. Umakoshi* Chem. Rec. 21, 469–479 (2021). [DOI: 10.1002/tcr.202000125]

25. Anion-Mediated Encapsulation-Induced Emission Enhancement of an IrIII Complex within a Resorcin[4]arene Hexameric Capsule. S. Horiuchi,* C. Matsuo, E. Sakuda, Y. Arikawa, G. H. Clever, K. Umakoshi* Dalton. Trans. 49, 8472–8477 (2020). [DOI: 10.1039/d0dt01485k]
Featured in the cover.

24. Stereoisomers of Homoleptic Dipyrrinatoplatinum(II) Complexes Having Arylborane Charge-Transfer Substituents: Synthesis, Characterization and Spectroscopic Properties. K. Takaki, E. Sakuda, A. Ito, S. Horiuchi, Y. Arikawa, K. Umakoshi* Chem. Lett. 49, 905–908 (2020). [DOI: 10.1246/cl.200258]

23. Photocatalytic CO2 reduction under visible-light irradiation by ruthenium CNC pincer complexes. Y. Arikawa,* I. Tabata, Y. Miura, H. Tajiri, Y. Seto, S. Horiuchi, E. Sakuda, K. Umakoshi* Chem. Eur. J. 26, 5603–5606 (2020). [DOI: 10.1002/chem.201905840]

22. Controlling the Electronic Structures and Excited-State Characteristics of Dipyrrinatoiridium(III) Complex by and Arylborane or an Arylamino Unit. K. Takaki, E. Sakuda,* A. Ito, S. Horiuchi, Y. Arikawa, K. Umakoshi* Inorg. Chem. 58, 14542–14550 (2019). [DOI: 10.1021/acs.inorgchem.9b02184]

21. Tunable Fullerene Affinity of Cages, Bowls and Rings Assembled by Pd(II) Coordination Sphere Engineering. B. Chen, S. Horiuchi, J. J. Holstein, J. Tessarolo, G. H. Clever* Chem. Eur. J. 25, 14921–14927 (2019). [DOI: 10.1002/chem.201903317]

20. Pd(II) Coordination Sphere Engineering: Pyridine Cages, Quinoline Bowls and Heteroleptic Pills Binding One or Two Fullerenes. B. Chen, J. J. Holstein, S. Horiuchi, W. G. Hiller, G. H. Clever* J. Am. Chem. Soc. 141, 8907–8913 (2019). [DOI: 10.1021/jacs.9b02207]

19. Photo-induced translocation of a Pdn moiety (n = 2, 7) on a conjugated polyene ligand. M. Yamashita, S. Horiuchi, K. Yamamoto, T. Murahashi* Dalton. Trans. 48, 13149–13153 (2019). [DOI: 10.1039/C9DT03073E]

18. Synthesis and Photophysical Properties of Butterfly-shaped Dinuclear Pt(II) complex having NHC-based Chelate Ligands. S. Moon, S. Horiuchi, E. Sakuda, A. Ito, Y. Arikawa, K. Umakoshi* Inorg. Chim. Acta. 492, 43–48 (2019). [DOI: 10.1016/j.ics.2019.04.045]

17. Encapsulation condition dependent photophysical properties of polypyridyl Ru(II) complexes within a hydrogen-bonded capsule. S. Horiuchi,* H. Tanaka, E. Sakuda, Y. Arikawa, K. Umakoshi* Dalton. Trans. 48, 5256–5160 (2019). [DOI: 10.1039/C9DT00737G]

16. Arrangement of a NO ligand and neighboring sulfur-containing species on a dinuclear ruthenium complex by ligand substitution and linkage isomerism of a dimethyl sulfoxide ligand. Y. Arikawa,* Y. Otsubo, T. Nakamura, N. Mitsuda, S. Horiuchi, E. Sakuda, K. Umakoshi Inorg. Chim. Acta. 490, 45–50 (2019). [DOI: 10.1016/j.ics.2019.02.036]

15. Extended Open-Chain Polyenides as Versatile Delocalized Anion Ligands for Metal Chain Clusters. M. Yamashita, Y. Kawasumi, Y. Tachibana, S. Horiuchi, K. Yamamoto, T. Murahashi* Chem. Eur. J. 25, 1212–1216 (2019). [DOI: 10.1002/chem.201805800]

14. U- to Z-shape isomerization in Pt2Ag2 framework containing pyridyl-NHC ligands. S. Horiuchi, S. Moon, E. Sakuda, A. Ito, Y. Arikawa, K. Umakoshi* Dalton. Trans. 47, 7113–7117 (2018). [DOI: 10.1039/C8DT01047A]
Featured in the cover.

13. Nitrite Reduction Cycle on a Dinuclear Ruthenium Complex Producing Ammonia. Y. Arikawa,* Y. Otsubo, H. Fujino, S. Horiuchi, E. Sakuda, K. Umakoshi J. Am. Chem. Soc. 140, 842–847 (2018). [DOI: 10.1021/jacs.7b12020]

12. Reversible Formation and Cleavage Pt→Ag Dative Bonds in a Pre-organized Cavity of Luminescent Heteropolynuclear Platinum(II) Complex. M. Ueda, S. Horiuchi, E. Sakuda, Y. Nakao, Y. Arikawa, K. Umakoshi* Chem. Commun. 53, 6405–6408 (2017). [DOI: 10.1039/C7CC03447D]
Featured in the cover.

11. Reactivity of a Methoxido-Ruthenium Complex Bearing a Pincer-Type Bis(carbene) Ligand toward Thiocyanate, Carbon Disulfide, and Isothiocyanate. Y. Arikawa,* T. Nakamura, T. Higashi, S. Horiuchi, E. Sakuda, K. Umakoshi Eur. J. Inorg. Chem. 2017, 881–884 (2017). [DOI: 10.1002/ejic.201601324]

10. Encapsulation and Enhanced Luminescence Properties of IrIII Complexes within a Hexameric Self-Assembled Capsule.  S. Horiuchi, H. Tanaka, E. Sakuda, Y. Arikawa, K. Umakoshi* Chem. Eur. J. 22, 17533–17537 (2016). [DOI: 10.1002/chem.201604016]
Featured in the cover.

9. Different structural preference of Ag(I) and Au(I) in neutral and cationic luminescent heteropolynuclear platinum(II) complexes: Z(U)-shaped Pt2M2 type vs. trinuclear PtM2 type. K. Nishihara, M. Ueda, A. Higashitani, Y. Nakao, Y. Arikawa, S. Horiuchi, K. Umakoshi* Dalton. Trans. 45, 4978–4982 (2016). [DOI: 10.1039/C6DT00320F]

8. Multinuclear metal-binding ability of a carotene. S. Horiuchi, Y. Tachibana, M. Yamashita, K. Yamamoto, K. Masai, K. Tanase, T. Matsutani, S. Kawamata, Y. Kurashige, T. Yanai, T. Murahashi* Nat. Commun. 6, 6742 (2015). [DOI: 10.1038/ncomms7742]

7. Gold(I) Catalysis within Self-Assembled Cages. S. Horiuchi* Bull. Jpn. Soc. Coord. Chem. 66, 31 (2015). [DOI: 10.4019/bjscc.66.31]

6. A Remarkable Organometallic Transformation on a Cage-Incarcerated Dinuclear Ruthenium Complex. S. Horiuchi, T. Murase, M. Fujita* Angew. Chem. Int. Ed. 51, 12029–12031 (2012). [DOI: 10.1002/anie.201206325]

5. Nonycovalent Trapping and Stabilization of Dinuclear Ruthenium Complexes within a Coordination Cage. S. Horiuchi, T. Murase, M. Fujita* J. Am. Chem. Soc. 133, 12445–12447 (2011). [DOI: 10.1021/ja205450a]

4. Diels-Alder Reaction of Inert Aromatic Compounds withinonycovalent Trapping and Stabilization of Dinuclear Ruthenium Complexes within a Coordination Cage. S. Horiuchi, T. Murase, M. Fujita* Chem. Asian J. 6, 1839–1847 (2011). [DOI: 10.1002/asia.201000842]

3. Remote chiral transfer into [2+2] and [2+4] cycloadditions within self-assembled molecular flasks. T. Murase, S. Peschard, S. Horiuchi, Y. Nishioka, M. Fujita* Supramol. Chem. 23, 199–208 (2011). [DOI: 10.1080/10610278.2010.521833]

2. Both [2+2] and [2+4] additions of inert aromatics via identical ternary host-guest complexes. S. Horiuchi, Y. Nishioka, T. Murase, M. Fujita* Chem. Commun. 46, 3460–3462 (2022). [DOI: 10.1039/c003191g]

1. Naphthalene Diels-Alder in a Self-Assembled Molecular Flask. T. Murase, S. Horiuchi, M. Fujita* J. Am. Chem. Soc. 132, 2866–2867 (2011). [DOI: 10.1021/ja9107275]

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