Original Paper

37. Faster Cyclization than Bridging Prefers the Formation of Pd6L3 Prisms Consisting of Porphyrin-based Tetratopic Ligands under Kinetic Contro. X. Zhang, S. Takahashi, K. Aratsu, T. Kojima, H. Sato, and S. Hiraoka*, submitted.

36. Navigated Self-assembly of a Pd2L4 Cage by Modulation of an Energy Landscape under Kinetic Control. T. Tateishi, S. Takahashi, A. Okazawa, V. Martí-Centelles, J. Wang, T. Kojima, P. L. Lusby,* H. Sato, and S. Hiraoka*, J. Am. Chem. Soc. 141, 19669 – 19676 (2019). [DOI: 10.1021/jacs.9b07779]

35. Bifurcation of Self-assembly Pathways to Sheet or Cage Controlled by Kinetic Template Effect. L. H. Foianesi-Takeshige, S. Takahashi, T. Tateishi, R. Sekine, A. Okazawa, W. Zhu, T. Kojima, K. Harano, E. Nakamura, H. Sato, and S. Hiraoka*, Commun. Chem. 2, 128 (2019).[DOI: 10.1038/s42004-019-0232-2] プレスリリース[Link]、Press release [Link]

34. Supramolecular Fluorescence Sensor for Liquefied Petroleum Gas. Y.-Y. Zhan, J. Liao, M. Kajita, T. Kojima, S. Takahashi, T. Takaya, K. Iwata, and S. Hiraoka*, Commun. Chem. 2, 107 (2019). [DOI: 10.1038/s42004-019-0212-6] プレスリリース[Link]、Press release[Link]、日本経済新聞電子版 [Link]、現代化学11月号「化学かわらばん」:超分子カプセルで液化天然ガスを検出[Link]

33. Polarizability and Isotope Effects on Dispersion Interactions in Water. Y.-Y. Zhan, Q.-C. Jiang, K. Ishii, T. Koide, T. Kojima, S. Takahashi, M. Tachikawa, S. Uchiyama, and S. Hiraoka*, Commun. Chem. 2, 141, (2019). [DOI: 10.1038/s42004-019-0242-0] プレスリリース [Link]、Press release [Link]

32. Self-assembly Processes of Octahedron-shaped Pd6L4 Cages. S. Komine, S. Takahashi, T. Kojima, H. Sato, and S. Hiraoka*J. Am. Chem. Soc. 141, 3178 – 3186 (2019). [DOI: 10.1021/jacs.8b12890]

31. Self-assembly Processes of Pd6L12 Cages. S. Komine, T. Tateishi, T. Kojima, H. Nakagawa, Y. Hayashi, S. Takahashi, and S. Hiraoka*, Dalton Trans. 48, 4139 – 4148 (2019). (selected as Inside Front Cover and Hot Paper) [DOI: 10.1039/C8DT04931A]

30. Self-assembly Process of a Quadruply Interlocked Palladium Cage. T. Tateishi, Y. Yasutake, T. Kojima, S. Takahashi, and S. Hiraoka*, Commun. Chem. 2, 25 (2019). [DOI10.1038/s42004-019-0123-6] プレスリリース[Link]、日本経済新聞電子版[Link]

29. Temperature-Controlled Repeatable Scrambling and Induced-Sorting of Building Blocks Between Cubic Assemblies. Y.-Y. Zhan, T. Kojima, K. Ishii, S. Takahashi, Y. Haketa, H. Maeda, S. Uchiyama, and S. Hiraoka*, Nature Commun. 10, 1440 (2019). [DOI: 10.1038/s41467-019-09495-1] プレスリリース[Link]、Press release [Link]、日本経済新聞電子版 [Link]

28. Self-Assembly of a Pd4L8 Double-Walled Square Takes Place through Two Kinds of Metastable Species. S. Kai, T. Tateishi, T. Kojima, S. Takahashi, and S. Hiraoka*, Inorg. Chem. 57, 13083 – 13086 (2018). [DOI: 10.1021/acs.inorgchem.8b02470]

27. Induced-fit Expansion and Contraction of a Self-assembled Nanocube Finely Responding to Neutral and Anionic Guests. Y.-Y. Zhan, T. Kojima, T. Nakamura, T. Takahashi, S. Takahashi, Y. Haketa, Y. Shoji, H. Maeda, T. Fukushima, and S. Hiraoka*, Nature Commun. 9, 4530 (2018). [DOI: 10.1038/s41467-018-06874-y] プレスリリース [Link], Press release [Link]、日本経済新聞 2018年11月7日,科学新聞 2018年 11月16日 [Link], Physics Buzz 19 Nov 2018.

26. Gram-Scale Synthesis of a C2v-Symmetric Hexaphenylbenzene with Three Different Types of Substituents. J. Liao, T. Kojima, S. Takahashi, and S. Hiraoka*, Asian J. Org. Chem. 7, 2057 – 2060 (2018). (selected as Cover Feature) [DOI: 10.1002/ajoc.201800448]

25. Two Dominant Self-assembly Pathways to a Pd3L6 Double-walled TriangleT. Tateishi, S. Kai, Y. Sasaki, T. Kojima, S. Takahashi, and S. Hiraoka*, Chem. Commun. 54, 7758 – 7761 (2018). (selected as Outside Back Cover) [DOI: 10.1039/C8CC02608D]

24. Selective Preparation of C2v-Symmetric Hexaphenylbenzene Derivatives Through Sequential Suzuki Coupling. K. Ogata, T. Kojima*, and S. Hiraoka*, Synlett 29, 1597 – 1600 (2018). [DOI: 10.1055/s-0037-1610024] (Highlighted in SYNFORM [Link])

23. Energy-Landscape-Independent Kinetic Trap of Incomplete Cage in the Self-assembly of a Pd2L4 Cage. M. Nakagawa, S. Kai, T. Kojima, and S. Hiraoka*, Chem. Eur. J. 24, 8804 – 8808 (2018). (selected as Hot Paper and Inside Cover[PDF]) [DOI: 10.1002/chem.201801183]

22. A Balance Between van der Waals and Cation-π Interactions That Stabilizes Hydrophobic Assemblies. Y.-Y. Zhan, T. Kojima, T. Koide, M. Tachikawa, and S. Hiraoka*, Chem. Eur. J. 24, 9130 – 9135 (2018). [DOI:10.1002/chem.201801376]

21. Importance of Molecular Meshing for the Stabilization of Solvophobic Assemblies. Y.-Y. Zhan, N. Tanaka, Y. Ozawa, T. Kojima, T. Mashiko, U. Nagashima, M. Tachikawa, and S. Hiraoka*, J. Org. Chem. 81, 5132 – 5137 (2018). [DOI: 10.1021/acs.joc.8b00495]

20. How Does Chiral Self-sorting Take Place in the Formation of Homochiral Pd6L8 Capsules Consisting of Cyclotriveratrylene-based Chiral Tritopic Ligands? S. Kai, T. Kojima, F. L. Thorp-Greenwood, M. J. Hardie, and S. Hiraoka*,  Chem. Sci9, 4104 – 4108 (2018). [DOI: 10.1039/C8SC01062E]

19. Chiral Self-sorting Process in the Self-assembly of Homochiral Coordination Cages from Axially Chiral Ligands .T. Tateishi, T. Kojima, and S. Hiraoka*, Commun. Chem. 1, 20 (2018) [DOI: 10.1038/s42004-018-0020-4]. プレスリリース[Link], 日本経済新聞電子版 [Link]

18. Hyperthermostable Cube-shaped Assembly in Water. Y.-Y. Zhan, K. Ogata, T. Kojima, T. Koide, K. Ishii, T. Mashiko, M. Tachikawa, S. Uchiyama, and S. Hiraoka*, Commun. Chem. 1, 14 (2018) [DOI: 10.1038/s42004-018-0014-2] プレスリリース[Link], 科学新聞, 化学工業日報[Link]

17. Semi-quantitative Evaluation of Molecular Meshing by Surface Analysis with Varying Probe Radii. N. Tanaka, Y.-Y. Zhan, Y. Ozawa, T. Kojima, T. Koide, T. Mashiko, U. Nagashima, M. Tachikawa, and S. Hiraoka*, Chem. Commun54, 3555–3558 (2018). (selected as Outside Back Cover) [DOI: 10.1039/c8cc00695d]

16. Flexibility of Components Alters the Self-assembly Pathway of Pd2L4 Coordination Cages. S. Kai, S. P. Maddala, T. Kojima, S. Akagi, K. Harano, E. Nakamura, and S. Hiraoka*, Dalton Trans. 47, 3258–3263 (2018) (selected as Outside Front Cover). [DOI: 10.1039/C8DT00112J

15. Multiple Pathways in the Self-assembly Process of a Pd4L8 Coordination Tetrahedron. T. Tateishi, T. Kojima, and S. Hiraoka*, Inorg. Chem. 57, 2686–2694 (2018). [DOI: 10.1021/acs.inorgchem.7b03085]

14. Self-assembly of a Pd4L8 Double-walled Square Partly Takes Place through the Formation of Kinetically Trapped Species. T. Tateishi, W. Zhu, L. H. Foianesi-Takeshige, T. Kojima, K. Ogata, and S. Hiraoka*, Eur. J. Inorg. Chem. 1192–1197 (2018). [DOI: 10.1002/ejic.201800037]

13. Steric Interaction between Neighboring Components Favors the Formation of Large Intermediates in the Self-Assembly Process of a Pd2L4 Capsule. S. Kai, M. Nakagawa, T. Kojima, X. Li, M. Yamashina, M. Yoshizawa, and S. Hiraoka*,  Chem. Eur. J. 24, 3965–3969 (2018). (selected as Hot Paper and Cover Feature) [DOI: 1002/chem.201705253]

12. Quantitative Analysis of Self-Assembly Process of Hexagonal Pt(II) Macrocyclic Complexes: Effect of Solvent and Components. A. Baba, T. Kojima, and S. Hiraoka*, Chem. Eur. J. 24, 838–847 (2018). (selected as Hot Paper, Front Cover and Cover Profile) [DOI: 10.1002/chem.201702955]

11. Quantitative Analysis of Self-Assembly Process of a Pd2L4 Cage Consisting of Rigid Ditopic Ligands. S. Kai, V. Marti-Centelles, Y. Sakuma, T. Mashiko, T. Kojima, U. Nagashima, M. Tachikawa, P. J. Lusby, and S. Hiraoka*, Chem. Eur. J. 24, 663–671 (2018). [DOI: 10.1002/chem.201704285]

10. Quantitative Analysis of Self-assembly Process of a Pd12L24 Coordination Sphere. S. Kai, T. Shigeta, T. Kojima, and S. Hiraoka*, Chem. Asian J. 12, 3203–3207 (2017). [DOI: 10.1002/asia.201701351]

9. The Effect of Solvent and Coordination Environment of Metal Source on the Self-Assembly Pathway of a Pd(II)-mediated Coordination Capsule. S. Kai, Y. Sakuma, T. Mashiko, T. Kojima, M. Tachikawa, and S. Hiraoka*, Inorg. Chem. 56, 12652–12663 (2017). [DOI: 10.1021/acs.inorgchem.7b02152]

8. Self-Assembly Process of Dodecanuclear Pt(II)-Linked Cyclic Hexagon. A. Baba, T. Kojima, and S. Hiraoka*, J. Am. Chem. Soc. 137, 7664–7667 (2015). [DOI: 10.1021/jacs.5b04852]

7. Mesityllithium and p-(Dimethylamino)phenyllithium for the Selective Alternate Trilithiation of the Hexaphenylbenzene Framework. T. Kojima* and S. Hiraoka*, Chem. Commun. 50, 10420–10423 (2014). [DOI: 10.1039/C4CC04520C]

6. Rate-Determining Step in the Self-Assembly Process of Supramolecular Coordination Capsules. Y. Tsujimoto, T. Kojima, and S. Hiraoka*, Chem. Sci. 5, 4167–4172 (2014). [DOI: 10.1039/C4SC01652A] (selected as Outside Back Cover)

5. Structural Dynamics of Overcrowded Alkene-based Molecular Motors during Thermal Isomerization. A. Cnossen, J. C. M. Kistemaker, T. Kojima, and B. L. Feringa*, J. Org. Chem. 79, 927–935 (2014). [DOI: 10.1021/jo402301j]

4. Selective Alternate Derivatization of the Hexaphenylbenzene Framework through a Thermodynamically Controlled Halogen Dance. T. Kojima* and S. Hiraoka*, Org. Lett. 16, 1024–1027 (2014). [DOI: 10.1021/ol500041j]

3. Synthesis of Triphosphatruxene via Sextuple Aromatic Nucleophilic Substitution and Simple Isolation of Stereoisomers. T. Kojima, S. Furukawa, H. Tsuji,* and E. Nakamura*, Chem. Lett. 43, 676–677 (2014). [DOI: 10.1246/cl.131195]

2. Molecular Dynamics and Principal Components Analysis for a Self-assembled Nanocube in Aqueous Solution. T. Mashiko, K. Yamada, T. Kojima, S. Hiraoka, U. Nagashima, and M. Tachikawa*, Chem. Lett. 43, 366–368 (2014). [DOI: 10.1246/cl.130928]

1. Synthesis of π-Conjugated Dendrimers Based on Azaborines. T. Agou, T. Kojima, J. Kobayashi, and T. Kawashima*, Org. Lett. 11, 3534–3537 (2009). [DOI: 10.1021/ol901035d]  


2. van der Waals相互作用を活用した物質合成. 小島 達央・平岡 秀一, 化学, 73, (9), 68–69 (2018).

1. キラルセルフソーティング の機構: どのようにエナンチオマーの選別が起こるのか. 立石 友紀・小島 達央・平岡 秀一, 現代化学, 9月号(570), 64–68 (2018).