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自己集合体の形成機構の解明 (Quantitative Analysis of Self-Assembly Process (QASAP)

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Flexibility of Components Alters the Self-assembly Pathway of Pd2L4 Coordination Cages, S. Kai, S. P. Maddala, T. Kojima, S. Akagi, K. Harano, E. Nakamura, and S. Hiraoka*, Dalton Trans.47, 3258–3263 (2018). (selected as Outside Front Cover). [DOI: 10.1039/C8DT00112J]

(University of Tokyo)

Prof. E. Nakamura

(University of Tokyo)

Prof. K. Haranao

Nakamura

collaborated with

Harano
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©2010 The Hiraoka Group. All Rights Reserved.

Two Dominant Self-assembly Pathways to a Pd3L6 Double-walled Triangle. T. Tateishi, S. Kai, Y. Sasaki, T. Kojima, S. Takahashi, and S. Hiraoka*, Chem. Commun. in press (selected as Back Cover) [DOI; ]

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Energy-Landscape-Independent Kinetic Trap of Incomplete Cage in the Self-assembly of a Pd2L4 Cage. M. Nakagawa, S. Kai, T. Kojima, and S. Hiraoka*, Chem. Eur. J. in press (selected as Hot Paper and Inside Cover). [DOI: 10.1002/chem.201801183]

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How Does Chiral Self-sorting Take Place in the Formation of Homochiral Pd6L8 Capsules Consisting of Cyclotriveratrylene-based Chiral Tritopic Ligands? S. Kai, T. Kojima, F. L. Thorp-Greenwood, M. J. Hardie, S. Hiraoka*, Chem. Sci. 9, 4104 – 4108 (2018). [DOI: 10.1039/C8SC01062E]

(University of Leeds, UK)

Prof. M. J. Hardie

Haridie

collaborated with

Unresolved Issues that Remain in Molecular Self-Assembly. S. Hiraoka*, Bull. Chem. Soc. Jpn. 91, 957–978 (2018). (Commemorative Accounts: Self-Organization). [DOI: 10.1246/bcsj.20180008]

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Chiral Self-sorting Process in the Self-assembly of Homochiral Coordination Cages from Axially Chiral Ligands. T. Tateishi, T. Kojima, and S. Hiraoka*, Commun. Chem. 1, 20 (2018). [DOI: 10.1038/s42004-018-0020-4]. プレスリリース[PDF], 日本経済新聞電子版[Link]

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Multiple Pathways in the Self-assembly Process of a Pd4L8 Coordination Tetrahedron, T. Tateishi, T. Kojima, and S. Hiraoka*, Inorg. Chem. 57, 2686–2694 (2018).. [DOI: 10.1021/acs.inorgchem.7b03085]

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Chiral Effects on the Final Step of an Octahedron-Shaped Coordination Capsule Self-Assembly. Y. Matsumura, S. Iuchi, S. Hiraoka, and H. Sato*, Phys. Chem. Chem. Phys. 20, 7383–7386 (2018) (selected as Hot Paper and Back Cover [PDF]). [DOI: 10.1039/C7CP08237A]

(Kyoto University)

Prof. H. Sato

collaborated with

HSato
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Self-assembly of a Pd4L8 Double-walled Square Partly Takes Place through the Formation of Kinetically Trapped Species, T. Tateishi, W. Zhu, L. H. Foianesi-Takeshige, T. Kojima, K. Ogata, and S. Hiraoka*, Eur. J. Inorg. Chem. 1192–1197 (2018). [DOI: 10.1002/ejic.201800037]

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(Tokyo Institute of Technology)

Prof. M. Yoshizawa

collaborated with

Yoshizawa

Steric Interaction between Neighboring Components Favors the Formation of Large Intermediates in the Self-Assembly Process of a Pd2L4 Capsule. S. Kai, M. Nakagawa, T. Kojima, X. Li, M. Yamashina, M. Yoshizawa, and S. Hiraoka*, Chem. Eur. J. 24, 3965 3969 (2018). (selected as Cover Feature) [DOI: 1002/chem.201705253]

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Quantitative Analysis of Self-Assembly Process of Hexagonal Pt(II) Macrocyclic Complexes: Effect of Solvent and Components. A. Baba, T. Kojima, and S. Hiraoka*, Chem. Eur. J. 24, 838–847 (2018). (selected as Hot Paper, Front Cover and Cover Profile) [DOI: 10.1002/chem.201702955]

Quantitative Analysis of Self-Assembly Process of a Pd2L4 Cage Consisting of Rigid Ditopic Ligands. S. Kai, V. Marti-Centelles, Y. Sakuma, T. Mashiko, T. Kojima, U. Nagashima, M. Tachikawa, P. J. Lusby, and S. Hiraoka*, Chem. Eur. J. 24, 663–671 (2018). [DOI: 10.1002/chem.201704285]

(Yokohama City Univeristy)

Prof. M. Tachikawa

Tachikawa1

(University of Edinburgh, UK)

Prof. P. J. Lusby

Lusby

collaborated with

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Quantitative Analysis of Self-assembly Process of a Pd12L24 Coordination Sphere. S. Kai, T. Shigeta, T. Kojima, and S. Hiraoka*, Chem. Asian J. 12, 3203–3207 (2017). [DOI: 10.1002/asia.201701351]

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The Effect of Solvent and Coordination Environment of Metal Source on the Self-Assembly Pathway of a Pd(II)-mediated Coordination Capsule. S. Kai, Y. Sakuma, T. Mashiko, T. Kojima, M. Tachikawa, and S. Hiraoka*, Inorg. Chem. 56, 12652-12663 (2017). [DOI: 10.1021/acs.inorgchem.7b02152]

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(Yokohama City Univeristy)

Prof. M. Tachikawa

Tachikawa

collaborated with

A Reaction Model on the Self-assembly Process of Octahedron-shaped Coordination Capsules. Y. Matsumura, S. Hiraoka, and H. Sato*, Phys. Chem. Chem. Phys. 19, 20338–20342 (2017). [DOI: 10.1039/c7cp03493h]

 

 

 

Graphical Abstract comming soon

(Kyoto University)

Prof. H. Sato

HSato1

collaborated with

What Do We Learn from the Molecular Self-Assembly Process?, S. Hiraoka*, Chem. Rec. 15, (6), 1144-1147 (2015) [DOI: 10.1002/tcr.201510005]

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Self-Assembly Process of Dodecanuclear Pt(II)-Linked Cyclic Hexagon, A. Baba, T. Kojima, and S. Hiraoka, J. Am. Chem. Soc. 137, 7664-7667 (2015). [DOI: 10.1021/jacs.5b04852]

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Rate-Determining Step in the Self-Assembly Process of Supramolecular Coordination Capsules, Y. Tsujimoto, T. Kojima, and S. Hiraoka*, Chem. Sci. 5, 4167-4172 (2014). [DOI: 10.1039/C4SC01652A] (selected as Back Cover)

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東京大学 大学院総合文化研究科 広域科学専攻 平岡研究室 (超分子化学研究室)

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自己集合体の形成機構の解明

ヘキサフェニルベンゼン誘導体の合成

分子ほぞ

分子自己集合の科学:形成機構の解明と新規自己集合体の形成

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QASPTitle

A Kinetics Study of Ligand Substitution Reaction on Dinuclear Platinum Complexes: Stochastic Versus Deterministic Approach, T. Iioka, S. Takahashi, Y. Yoshida, Y. Matsumura, S. Hiraoka, and H. Sato*, submitted.

(Kyoto University)

Prof. H. Sato

collaborated with

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キラルセルフソーティング の機構:エナンチオマーの選別が自発的に起こるメカニズム, 立石 友紀・小島 達央・平岡 秀一, 現代化学, 印刷中 (2018)

©2010 The Hiraoka Group. All Rights Reserved.

自己組織化の過程を調べる, 平岡秀一,現代化学, 3, 30–35 (2015).

 

 

 

Graphical Abstract comming soon

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Self-assembly Processes of Pd(II)- and Pt(II)-linked Discrete Self-assemblies Revealed by QASAP, S. Hiraoka*, submitted (Invited Account)

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