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自己集合体の形成機構の解明 (Quantitative Analysis of Self-Assembly Process (QASAP)

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PCCP2019
Dalton

Self-assembly Process of a Pd4L8 Quadruply Interlocked Cage.

T. Tateishi, Y. Yasutake, T. Kojima, S. Takahashi, and S. Hiraoka*
Commun. Chem. 2, 25 (2019). [DOI: 10.1038/s42004-019-0123-6]
プレスリリース[Link]、日本経済新聞電子版 [Link]

Self-assembly Processes of Pd6L12 Cages.

S. Komine, T. Tateishi, T. Kojima, H. Nakagawa, Y. Hayashi, S. Takahashi, and S. Hiraoka*
Dalton Trans. 48, 4139 – 4148 (2019). [DOI: 10.1039/C8DT04931A]
selected as Inside Front Cover

(Kyoto University)

Prof. H. Sato

HSato2a1

collaborated with

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©2010 The Hiraoka Group. All Rights Reserved.

Rate-Determining Step in the Self-Assembly Process of Supramolecular Coordination Capsules.

Y. Tsujimoto, T. Kojima, and S. Hiraoka*,
Chem. Sci. 5, 4167-4172 (2014). [DOI: 10.1039/C4SC01652A]
selected as Back Cover
BackCover1
TOC8a

自己組織化の過程を調べる

平岡秀一
現代化学, 3, 30–35 (2015).

Self-Assembly Process of Dodecanuclear Pt(II)-Linked Cyclic Hexagon.

A. Baba, T. Kojima, and S. Hiraoka
J. Am. Chem. Soc. 137, 7664-7667 (2015). [DOI: 10.1021/jacs.5b04852]
TOC9a

What Do We Learn from the Molecular Self-Assembly Process?

S. Hiraoka*
Chem. Rec. 15, 1144-1147 (2015) [DOI: 10.1002/tcr.201510005]
TOC10a

A Reaction Model on the Self-assembly Process of Octahedron-shaped Coordination Capsules.

Y. Matsumura, S. Hiraoka, and H. Sato*
Phys. Chem. Chem. Phys. 19, 20338–20342 (2017). [DOI: 10.1039/c7cp03493h]

(Kyoto University)

Prof. H. Sato

HSato1a

collaborated with

The Effect of Solvent and Coordination Environment of Metal Source on the Self-Assembly Pathway of a Pd(II)-mediated Coordination Capsule.

S. Kai, Y. Sakuma, T. Mashiko, T. Kojima, M. Tachikawa, and S. Hiraoka*
Inorg. Chem. 56, 12652-12663 (2017). [DOI: 10.1021/acs.inorgchem.7b02152]
TOC12

(Yokohama City Univeristy)

Prof. M. Tachikawa

Tachikawa2

collaborated with

Quantitative Analysis of Self-assembly Process of a Pd12L24 Coordination Sphere.

S. Kai, T. Shigeta, T. Kojima, and S. Hiraoka*
Chem. Asian J. 12, 3203–3207 (2017). [DOI: 10.1002/asia.201701351]
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TOC2a

(Yokohama City Univeristy)

Prof. M. Tachikawa

collaborated with

Tachikawa1a
Lusby1

Prof. P. J. Lusby

(University of Edinburgh, UK)

Quantitative Analysis of Self-Assembly Process of a Pd2L4 Cage Consisting of Rigid Ditopic Ligands.

S. Kai, V. Marti-Centelles, Y. Sakuma, T. Mashiko, T. Kojima, U. Nagashima, M. Tachikawa, P. J. Lusby, and S. Hiraoka*
Chem. Eur. J. 24, 663–671 (2018). [DOI: 10.1002/chem.201704285]

Quantitative Analysis of Self-Assembly Process of Hexagonal Pt(II) Macrocyclic Complexes: Effect of Solvent and Components.

A. Baba, T. Kojima, and S. Hiraoka*
Chem. Eur. J. 24, 838–847 (2018). [DOI: 10.1002/chem.201702955]
selected as Hot Paper, Front Cover and Cover Profile
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(Tokyo Institute of Technology)

Prof. M. Yoshizawa

collaborated with

Yoshizawa1

Steric Interaction between Neighboring Components Favors the Formation of Large Intermediates in the Self-Assembly Process of a Pd2L4 Capsule.

S. Kai, M. Nakagawa, T. Kojima, X. Li, M. Yamashina, M. Yoshizawa, and S. Hiraoka*
Chem. Eur. J. 24, 3965 3969 (2018). [DOI: 1002/chem.201705253]
selected as Cover Feature

Self-assembly of a Pd4L8 Double-walled Square Partly Takes Place through the Formation of Kinetically Trapped Species.

T. Tateishi, W. Zhu, L. H. Foianesi-Takeshige, T. Kojima, K. Ogata, and S. Hiraoka*
Eur. J. Inorg. Chem. 1192–1197 (2018). [DOI: 10.1002/ejic.201800037]
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collaborated with

PCCP2018backcover1
HSato3

Prof. H. Sato

(Kyoto University)

Chiral Effects on the Final Step of an Octahedron-Shaped Coordination Capsule Self-Assembly.

Y. Matsumura, S. Iuchi, S. Hiraoka, and H. Sato*
Phys. Chem. Chem. Phys. 20, 7383–7386 (2018). [DOI: 10.1039/C7CP08237A]
selected as Hot Paper and Back Cover [PDF]

Multiple Pathways in the Self-assembly Process of a Pd4L8 Coordination Tetrahedron.

T. Tateishi, T. Kojima, and S. Hiraoka*
Inorg. Chem. 57, 2686–2694 (2018). [DOI: 10.1021/acs.inorgchem.7b03085]
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Flexibility of Components Alters the Self-assembly Pathway of Pd2L4 Coordination Cages.

S. Kai, S. P. Maddala, T. Kojima, S. Akagi, K. Harano, E. Nakamura, and S. Hiraoka*
Dalton Trans. 47, 3258–3263 (2018). [DOI: 10.1039/C8DT00112J]
selected as Outside Front Cover

(University of Tokyo)

(University of Tokyo)

Prof. K. Haranao

Prof. E. Nakamura

Nakamura1

collaborated with

Harano1
TOC7a
Daltoncover2018a

Chiral Self-sorting Process in the Self-assembly of Homochiral Coordination Cages from Axially Chiral Ligands.

T. Tateishi, T. Kojima, and S. Hiraoka*
Commun. Chem. 1, 20 (2018). [DOI: 10.1038/s42004-018-0020-4].
プレスリリース[Link] 日本経済新聞電子版[Link]

Unresolved Issues that Remain in Molecular Self-Assembly.

S. Hiraoka*
Bull. Chem. Soc. Jpn. 91, 957–978 (2018). [DOI: 10.1246/bcsj.20180008]
Commemorative Accounts: Self-Organization
TOC11a

How Does Chiral Self-sorting Take Place in the Formation of Homochiral Pd6L8 Capsules Consisting of Cyclotriveratrylene-based Chiral Tritopic Ligands?

S. Kai, T. Kojima, F. L. Thorp-Greenwood, M. J. Hardie, and S. Hiraoka*
Chem. Sci. 9, 4104 – 4108 (2018). [DOI: 10.1039/C8SC01062E]

(University of Leeds, UK)

Prof. M. J. Hardie

collaborated with

Haridie1

(Kyoto University)

Prof. H. Sato

HSato2b

collaborated with

A Kinetics Study of Ligand Substitution Reaction on Dinuclear Platinum Complexes: Stochastic Versus Deterministic Approach

T. Iioka, S. Takahashi, Y. Yoshida, Y. Matsumura, S. Hiraoka, and H. Sato*
J. Comput. Chem. 1, 279 – 285 (2019). [DOI: 10.1002/jcc.25588]

キラルセルフソーティング の機構:どのようにエナンチオマーの選別が起こるのか,

立石 友紀・小島 達央・平岡 秀一
現代化学, 9月号(570), 64–68 (2018).

Two Dominant Self-assembly Pathways to a Pd3L6 Double-walled Triangle.

T. Tateishi, S. Kai, Y. Sasaki, T. Kojima, S. Takahashi, and S. Hiraoka*
Chem. Commun. 54, 7758 – 5561 (2018). [DOI: 10.1039/C8CC02608D]]
selected as Back Cover

Energy-Landscape-Independent Kinetic Trap of Incomplete Cage in the Self-assembly of a Pd2L4 Cage.

M. Nakagawa, S. Kai, T. Kojima, and S. Hiraoka*
. Eur. J. 24, 8804–8808 (2018). [DOI: 10.1002/chem.201801183]
selected as Hot Paper and Inside Cover

Self-Assembly of a Pd4L8 Double-Walled Square Takes Place through Two Kinds of Metastable Species.

S. Kai, T. Tateishi, T. Kojima, S. Takahashi, and S. Hiraoka*
Inorg. Chem. 57, 13083 – 13086 (2018). [DOI: 10.1021/acs.inorgchem.8b02470]

A Stochastic Model Study on the Self-Assembly Process of a Pd2L4 Cage Consisting of Rigid Ditopic Ligands.

S. Takahashi*, Y. Sasaki, S. Hiraoka*, and H. Sato*
Phys. Chem. Chem. Phys. 21, 6341 – 6347 (2019). [DOI: 10.1039/C8CP06102E ]
selected as Outside Back Cover

Self-assembly Processes of Pd(II)- and Pt(II)-linked Discrete Self-assemblies Revealed by QASAP.

S. Hiraoka*
Isr. J. Chem. in press. [DOI: 10.1002/ijch.201800073]
(Invited Account)

H

東京大学 大学院総合文化研究科 広域科学専攻 平岡研究室 (超分子化学研究室)

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自己集合体の形成機構の解明

Self-assembly processes

(QASAP)

ヘキサフェニルベンゼン誘導体の合成

Syntheis of HPB derivatives

分子ほぞ - ナノキューブ

Molecular "Hozo" and Nanocube

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QASPTitle

Self-assembly Processes of Octahedron-shaped Pd6L4 Cages.

S. Komine, S. Takahashi, T. Kojima, H. Sato, and S. Hiraoka*
J. Am. Chem. Soc. 141, 3178 – 3186 (2019). [DOI: 10.1021/jacs.8b12890]

(Kyoto University)

Prof. H. Sato

HSato2a1a

collaborated with

分子自己集合の科学:「分子ほぞ」・自己集合の機構解明・散逸系自己集合

JACSTOC
CommunChemTOC
DaltonTOC
PCCPTOC
InorgChemTOC
JCCTOC
CCTOC
ChemEurJTOC
ChemSciTOC
CommunChemTOC1
PCCPTOC1
PCCPTOC2
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