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Publications

Original Papers

Selected Publications

  • Self-Assembly Process of Dodecanuclear Pt(II)-Linked Cyclic Hexagon
    A. Baba, T. Kojima, and S. Hiraoka
    J. Am. Chem. Soc. 137, 7664-7667 (2015). [DOI: 10.1021/jacs.5b04852]
  • Rate-Determining Step in the Self-Assembly Process of Supramolecular Coordination Capsules
    Y. Tsujimoto, T. Kojima, and S. Hiraoka
    Chem. Sci. 5, 4167-4172 (2014). [DOI: 10.1039/C4SC01652A] (Back Cover)
  • In-water Truly Monodisperse Aggregation of Gear-Shaped Amphiphiles Based on Hydrophobic Surface Engineering
    S. Hiraoka, T. Nakamura, M. Shiro, and M. Shionoya
    J. Am. Chem. Soc. 132, 13223-13225 (2010). [web][Supporting Information]
  • A Molecular Double Ball Bearing: A Ag(I)-Pt(II) Dodecanuclear Quadruple-Decker Complex having Three Rotors
    S. Hiraoka, Y. Hisanaga, M. Shiro, and M. Shionoya
    Angew. Chem. Int. Ed. 49, 1669-1673 (2010). [web][Supporting Information] (Highlighted in SYNFACTS)
  • Site-Selective Internally-Cross-Linking between Mercury(II)-Centered Vertices of an Octahedral Hexanuclear Mercury (II) Capsule by a Rod-Shaped Ditopic Ligand
    S. Hiraoka, M. Kiyokawa, S. Hashida, and M. Shionoya
    Angew. Chem. Int. Ed. 49, 138-143 (2010). [web][Supporting Information]
  • Induced-Fit Formation of a Tetrameric Organic Capsule consisting of Hexagram-Shaped Amphiphile
    S. Hiraoka, K. Harano, T. Nakamura, M. Shiro, and M. Shionoya
    Angew. Chem. Int. Ed. 48, 7006-7009, (2009). [web][Supporting Information]
  • Template-Directed Synthesis of a Covalent Organic Capsule based on a 3 nm-Sized Metallo-Capsule
    S. Hiraoka, Y. Yamauchi, R. Arakane, and M. Shionoya
    J. Am. Chem. Soc. 131, 11646-11647 (2009). [web][Supporting Information] (Highlighted in Nature Chemistry)
  • Alternate Arrangement of Two Different Metals at Chemically-Equivalent Biding Sites on a Circle
    S. Hiraoka, M. Goda, and M. Shionoya
    J. Am. Chem. Soc. 131, 4592-4593 (2009). [web][Supporting Information]
  • A Self-Assembled Organic Capsule Formed from the Union of Six Hexagram-Shaped Amphiphile Molecules
    S. Hiraoka, K. Harano, M. Shiro, and M. Shionoya
    J. Am. Chem. Soc. 130, 14368-14369 (2008). [web][Supporting Information]
  • Ti(IV)-Centerd Interconversion between Pd(II), Ti(IV)-containing Ring and Cage Molecules
    S. Hiraoka, Y. Sakata, and M. Shionoya
    J. Am. Chem. Soc. 130, 5300-5301 (2008). [web][Supporting Information]
  • Ranging Correlated Motion (1.5 nm) of Two Coaxially Arranged Rotors Mediated by Helix Inversion of a Supramolecular Transmitter
    S. Hiraoka, E. Okuno, T. Tanaka, M. Shiro, and M. Shionoya
    J. Am. Chem. Soc. 130, 9089-9098 (2008). [web][Supporting Information] (Highlighted in Science)
  • 3nm-Scale molecular Switching between Fluorescent Capsule and Non-Fluorscent Cage
    K. Harano, S. Hiraoka, and M. Shionoya
    J. Am. Chem. Soc. 129, 5300-5301 (2007). [web][Supporting Information]
  • Electrostatically Controlled Hierarchical Arrangement of Monocationic Silver(I) and Dicationic Mercury(II) Ions between Disk-Shaped Template Ligands
    S. Hiraoka, T. Tanaka, and M. Shionoya
    J. Am. Chem. Soc. 128, 13038-13039 (2006). [web][Supporting Information]
  • Isostructural Coordination Capsules for a Series of 10 Different d5-d10 Transition-Metal Ions
    S. Hiraoka, K. Harano, M. Shiro, Y. Ozawa, N. Yasuda, K. Toriumi, and M. Shionoya
    Angew. Chem. Int. Ed. 45, 6488-6491 (2006). [web][Supporting Information] (VIP paper & Cover Picture)
  • Quantitative Dynamic Interconversion between Ag(I)-Mediated Capsule and Cage Complexes Accompanying Guest Encapsulation/Release
    S. Hiraoka, K. Harano, M. Shiro, and M. Shionoya
    Angew. Chem. Int. Ed. 44, 2727-2731 (2005). [web][Supporting Information]
  • A Molecular Ball Bearing Mediated by Multi-Ligand Exchange in Concert
    S. Hiraoka, K. Hirata, and M. Shionoya
    Angew. Chem. Int. Ed. 43, 3814-3818 (2004). [web][Supporting Information]
  • Heterotopic Assemblage of Two Different Disk-Shaped Ligands through Silver(I) Complexation: Ligand Exchange Driven Molecular Motion
    S. Hiraoka, M. Shiro, and M. Shionoya
    J. Am. Chem. Soc. 126, 1214-1218 (2004). [web][Supporting Information] (Highlighted in Nature)
  • Quantitative Formation of Sandwich-Shaped Trinuclear Silver(I) Complexes and Dynamic Nature of Their P⇄M Flip Motion in Solution
    S. Hiraoka, K. Harano, T. Tanaka, M. Shiro, and M. Shionoya
    Angew. Chem. Int. Ed. 42, 5182-5184 (2003). [web][Supporting Information]

 

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